高热硫酸溶解重量法测定矿石中的钡     

范福南  邢富  范秀娥 《岩矿测试》2002,21(3):219-222

利用BaSO4在高热H2 SO4中能定量地形成液态Ba(HSO4) 2 ,而当含Ba(HSO4) 2 的浓H2 SO4溶液被稀释时 ,又能重新定量析出BaSO4这一性质 ,拟定出高热H2 SO4溶解重量法测定矿石中的钡。方法用于矿石、重晶石单矿物中BaO和BaSO4的测定 ,结果与碱熔BaSO4重量法、BaCrO4容量法、外检结果相一致 ,精密度试验结果 ,相对标准偏差RSD(n =1 0 ) <5 %。  相似文献   

柴达木盆地三湖地区第四系生物气源岩中可溶有机质丰度及地质意义   总被引：3，自引：0，他引：3       下载免费PDF全文

张英  李剑  张奎  关平  李谨  王晓波 《地质学报》2007,81(12):1716-1722

柴达木盆地东部第四系生物气源岩有机质丰度是控制该区生物气资源的关键因素。通过重新设计实验流程,建立了针对未成熟生物气源岩的有机质丰度评价方法。柴达木盆地第四系生物气源岩可溶有机质含量约是不溶有机质含量的2.6倍,有机质大部分以可溶的形式存在。鉴于未成熟生物气源岩有机质赋存形式的特殊性,提出了柴达木盆地东部第四系生物气源岩的有机质丰度评价标准。大量存在的可溶有机质揭示柴达木盆地东部地区第四系仍处于生物甲烷生成阶段,较高的气源岩有机质丰度为生物气勘探提供了重要的资源保障。  相似文献   

铅电解原料工业硅氟酸中硫酸根的快速测定     

肖晓辉 《岩矿测试》2007,26(5):421-422

用硝酸钾溶液沉淀硅氟酸根离子，分离大量的基体，滤液与氯化钡在保护剂的作用下，形成硫酸钡悬浊液，用分光光度计于波长440nm处测定其吸光度。方法的表观摩尔吸光系数为1.7×10^5L·mol^-1·cm^-1，测定范围为0、04～0．48g／L。应用于铅电解原料工业硅氟酸中硫酸根的测定，结果与重量法基本一致，7次测定的相对标准偏差小于7％，加标回收率为97．5％～101．7％。  相似文献   

Quaternary biogenic opal records in the South China Sea: Linkages to East Asian monsoon, global ice volume and orbital forcing   总被引：3，自引：0，他引：3  

WANG RuJian  JIAN ZhiMin  XIAO WenShen  TIAN Jun  LI JianRu  CHEN RongHua  ZHENG YuLong & CHEN JianFang State Key Laboratory of Marine Geology  Tongji University  Shanghai  China  The Key Laboratory of Submarine Geoscience  State Oceanic Administration  Hangzhou  China 《中国科学D辑(英文版)》2007,50(5):710-724

Particulate fluxes investigated in the central South China Sea (SCS) during 1993―1996 indicate that opal flux can be used to show primary productivity change, which provides a foundation for tracing the evolutionary relationship between the surface productivity and East Asian monsoon in the SCS during the late Quaternary glacial and interglacial periods. Based on the studies of opal % and their mass accumulation rates (MAR) at the six sites recovered from the SCS during the “Resolution” ODP Leg 184 and “Sonne” 95 cruise of the Sino-Germany cooperation, opal % and their MARs increased evidently in the northern sites since 470―900 ka, and they enhanced and reduced, respectively, during the glacial and interglacial periods. Whereas they increased obviously in the southern sites since 420―450 ka, and they augmented and declined, respectively, during the interglacial and glacial periods. The vari- ability in opal % and their MARs in the late Quaternary glacial cyclicity indicate the “seesaw” pattern of surface productivity in the SCS. The winter monsoon intensified during the glacial periods, surface productivity increased and decreased, respectively, in the northern and southern SCS. The summer monsoon strengthened during the interglacial periods, surface productivity increased and decreased, respectively, in the southern and northern SCS. The cross spectral analyses between the opal % in the northern and southern SCS during the Quaternary and global ice volume (δ 18O) and orbital forcing (ETP) indicate that the East Asian winter and summer monsoons could be ascribed to the different drive mechanisms. On the orbital time scale, the global ice volume change could be a dominant factor for the winter monsoon intension and temporal variations. As compared with the winter monsoon, the correlative summer solar radiation with the obliquity and precession in the Northern Hemisphere could be a mostly controlling factor for the summer monsoon intension and temporal variations.  相似文献   

Controls on soil pore water solutes: An approach for distinguishing between biogenic and lithogenic processes     

Art F. White  Marjorie S. Schulz  Davison V. Vivit  Alex E. Blum  David A. Stonestrom 《Journal of Geochemical Exploration》2006,88(1-3):363

Spatial and temporal variations in pore water compositions are characterized for a deep regolith profile developed on a marine terrace chronosequence near Santa Cruz California. Variations are resolved in terms of the dominance of either a lithogenic process, i.e. chemical weathering, or a biogenic process, i.e. plant nutrient cycling. The concept of elemental fractionation is introduced describing the extent that specific elements are mobilized and cycled as a result of these processes.  相似文献   

Marine organic geochemistry of the Eastern Mediterranean: 1. Aliphatic and polyaromatic hydrocarbons in Cretan Sea surficial sediments   总被引：1，自引：0，他引：1  

Alexandra Gogou  Ioanna Bouloubassi  Euripides G. Stephanou   《Marine Chemistry》2000,68(4)

As part of a lipid biogeochemical study, aliphatic and polyaromatic hydrocarbons were determined in surficial sediments from the Cretan Sea (South Aegean Sea) in the Eastern Mediterranean. Total concentrations of both aliphatic (AHC) and polyaromatic (PAH) hydrocarbons were low (562–5697 and 14.6–158.5 ng/g, respectively) with respect to other coastal sediments worldwide and compare with concentrations found in open sea areas. The composition of AHC was dominated by unresolved complex mixture (UCM) indicating the presence of petroleum-related hydrocarbon inputs as confirmed by the detection of specific α,β-hopanes. PAH consisted mainly of pyrolytic four- to five-ring compounds. UCM and PAH amounts revealed that Cretan Sea receives low supply of anthropogenic material compared to NW Mediterranean. The spatial distributions of AHC and PAH indicated that urban run-off and transport from the continental self are the major input pathway of anthropogenic and biogenic hydrocarbons from terrestrial sources in the near shore area, whereas atmospheric transport might be the significant source of hydrocarbons in the deep area.  相似文献   

南沙群岛海域以钡为指标的古生产力研究   总被引：1，自引：0，他引：1  

陈绍勇  田正隆  龙爱民  吴云华 《海洋学报》2005,27(4):53-58

对南沙群岛海域3个站位沉积物柱样中的钡、钛元素进行了分析,以AMS-14C_orc(有机碳)方法进行沉积物年代测定.对钡、钛元素的平面和深度分布特征进行研究发现,其中2个站位生源钡变化趋势明显,在距2800a左右生源钡含量开始明显升高.另一个站位钡的变化趋势比较复杂,结合对稀土元素、钛和其他过渡金属元素的分析,认为主要是由于该站位沉积物中陆源组分含量较高、沉积环境复杂所致.根据钡的古生产力计算模型估算了2个站位的古生产力状况,同时探讨了2个站位的古生产力变化的影响因素,认为这2个站位古生产力变化可能与全新世晚期的气候变冷事件有关.  相似文献   

西太平洋马尔库斯-威克海山区沉积物中生物硅含量分布          下载免费PDF全文

孟凡盛  倪建宇  姚旭莹 《海洋学研究》2019,37(4):60-67

分析了大洋40航次在西太平洋马尔库斯-威克海山区山间海盆采集的表层沉积物中生物硅和有机质的含量,并对其分布特征和来源进行了初步的研究。结果表明,马尔库斯-威克海山区附近海域深海表层沉积物中生物硅含量总体较低,含量在0.88%～12.41%之间,平均含量为2.19%,分布上呈现西南含量高,向东北方向递减的趋势;深海表层沉积物中有机碳含量较低,δ¹³C同位素组成分布与生物硅相同。沉积物柱状样的研究表明研究区在过去的100～200 ka期间表层水体中硅质生物的初级生产力是逐渐增加的。  相似文献   

Ba同位素分析方法综述     

田兰兰  于慧敏  南晓云  黄方 《高校地质学报》2021,27(3):289-305

随着实验技术的进步以及多接收电感耦合等离子体质谱仪（MC-ICP-MS）和热电离质谱仪（TIMS）的发展,近年来Ba 同位素的分析方法取得了显著进展。分析精度（δ^138/134Ba,2SD）从之前的1 ‰ 提高到好于0.05 ‰。文章综述了近年来高精度Ba 同位素分析方法（溶液法）的发展历程,总结了国内外实验室关于不同类型样品的消解、Ba 元素化学纯化流程以及Ba 同位素质谱测定等方法,并对国内外多个实验室已发表的各类标准物质的Ba 同位素组成进行统计。研究结果可为Ba 同位素激光原位分析提供参考,为后续分馏机理解析和应用研究提供技术支撑。  相似文献   

Annual Variations of Biogenic Element Contents of Manila Clam （Ruditapes philippinarum） Bottom-Cultivated in Jiaozhou Bay,China     

ZAN Xiaoxiao XU Binduo ZHANG Chongliang REN Yiping 《青岛海洋大学学报(英文版)》2014,(4):637-646

Manila clam （Ruditapes philippinarum） was monthly sampled from its benthic aquaculture area in Jiaozhou Bay from May 2009 to June 2010.The annual variations of major elemental composition,organic content,fatness and element ratio of Manila clam were examined.The element removal effect of clam farming in Jiaozhou Bay was analyzed based on natural mortality and clam harvest.The results indicated that the variation trend of carbon content in shell （Cshell） was similar to that in clam （Cclam）.Such a variation was higher in summer and autumn than in other seasons,which ranged from 9.10±0.13 to 10.38 ± 0.09 mmol g^-1 and from 11.28 ±0.29 to 12.36±0.06 mmol g 1,respectively.Carbon content of flesh （Cflnesh） showed an opposite variation trend to that of shell in most months,varying from 29.42 ± 0.05 to 33.64 ± 0.62 mmol g^-1.Nitrogen content of shell （Nshell） and flesh （Nflesh） changed seasonally,which was relatively low in spring and summer.Nshell and Nflesh varied from 0.07 ±0.009 to 0.14±0.009 mmol g^-1 and from 5.46 ± 0.12 to 7.39 ± 0.43 mmol g^-1,respectively.Total nitrogen content of clam ranged from 0.50 ± 0.003 to 0.76 ± 0.10 mmol g^-1 with a falling tend except for a high value in March 2010.Phosphorus content of clam （Nclam） fluctuated largely,while phosphorus content of shell （Pshell） was less varied than that of flesh （Pflesh）.Pshell varied from 0.006±0.001 to 0.016±0.001 mmol g^-1; while Pflesh fluctuated between 0.058±0.017 and 0.293±0.029mmolg^-1.Pclam ranged from 0.015±0.002 to 0.041 ±0.006mmolg^-1.Carbon and nitrogen content were slightly affected by shell length,width or height.Elemental contents were closely related to the reproduction cycle.The removal amounts of carbon,nitrogen and phosphorus from clam harvest and natural death in Jiaozhou Bay were 2.92× 10^4t,1420t and 145 t,respectively.The nutrient removal may aid to reduce the concentrations of nitrogen and phosphorus,the main causes of eutrophication,and to maintain the ecosystem health of J  相似文献